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[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium

CAS: 802912-44-3

Molecular Formula: C29H34Cl2N3Ru

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[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium - Names and Identifiers

Name [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium
Synonyms 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ide,dichloro(3-pyridin-2-ylpropylidene)ruthenium
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl)propylidene]ruthenium(II)
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium(II)
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl)propylidene]ruthenium(ii)
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl-KN)propylidene-KC]ruthenium(II)
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl- N)propylidene- C]ruthenium(II)
Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridi nyl-kN)propylidene-kC]-, (SP-5-43)-
CAS 802912-44-3
InChI InChI=1S/C21H27N2.C8H9N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-5-8-6-3-4-7-9-8;;;/h9-13H,7-8H2,1-6H3;1,3-4,6-7H,2,5H2;2*1H;/q-1;;;;+2/p-2

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium - Physico-chemical Properties

Molecular FormulaC29H34Cl2N3Ru
Molar Mass596.58
Melting Point190.5-199.0°C
Storage Condition2-8°C

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium - Risk and Safety

WGK Germany3

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium - Introduction



Nature:
-Chemical formula: C39H44Cl2N4Ru
-Molecular weight: 748.76g/mol
-Appearance: Yellow crystal or yellow powder
-Melting point: 150-152°C
-insoluble in water, but soluble in organic solvents such as methylene chloride, carbon disulfide and methanol.

Use:
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium belongs to NHC ruthenium complex, which is commonly used as catalyst in organic synthesis and catalytic reaction, and has the following typical applications:
1. Synthesis of complex organic molecules: NHC ruthenium complexes can be used to catalyze the synthesis of complex compounds, such as natural product synthesis, drug synthesis, etc.
2. carbon-carbon coupling reaction: NHC ruthenium complex can promote carbon-carbon coupling reaction, such as Suzuki reaction, Heck reaction and so on.
3. Hydrogenation and oxidation reactions: NHC ruthenium complexes can be used to catalyze asymmetric hydrogenation and oxidation reactions.

Preparation Method:
the preparation of [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium generally adopts the method of reacting metal precursors with ligands, and a common preparation method is as follows:
1. Ruthenium chloride is reacted with a ligand in a solvent to obtain an intermediate.
2. After appropriate subsequent reaction and treatment, the target product is obtained.

Safety Information:
- [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium should be considered as organometallic compounds, potentially toxic and irritant.
-During the operation, good laboratory practices and measures should be taken, such as wearing protective glasses and gloves.
-Store and handle the compound properly to avoid contact with combustibles, oxidants and acidic materials.
-The information provided is for reference only. Please read the relevant literature carefully under specific experimental conditions and use it under the guidance of qualified laboratory operators.
Last Update：2024-04-09 15:18:00
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium
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Shanghai Yuanye Bio-Technology Co., Ltd.
Product Name: (1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDA& Visit Supplier Webpage Request for quotation
CAS: 802912-44-3
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
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[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium
Hodgsons Sublaprint Yellow 70000
(E)-hept-4-enoic acid
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